Steam and Amazon and others let you “buy” a streaming copy of the show, which is also nice because
1- this is often much cheaper than collector Blu-rays, and
2- there's no physical copy so maybe a larger slice (of the smaller pie) goes to the publisher.
The only downside compared to "buy and donate to library" is the loss of the buzz generated by the library circulating it.
I just finished "Your Lie in April" anime and loved it so so so much that $130 dollars are firing lasers at my pants pocket, wanting to fly to A-1 Pictures/Sony and its backers. $130 *per* *set*, and there's *two* sets for the whole series.
(And no, I won't buy the Asian DVD boxset.)
Maybe I'll buy the manga, even though it's the anime I'd really like to support.
First world problems :).